Which of the following reagents convert the acid chloride into aldehyde? CH3−CH2−CH2−CO−Cl→CH3−CH2−CH2−CHO
A
H2,Pd,BaSO4
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B
(CH3−CH2−CH2−CH2)3SnH
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C
LiAlH4
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D
NaH
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Solution
The correct option is AH2,Pd,BaSO4 Hydrogenation of acid chloride over palladium catalyst supported on barium sulphate gives an aldehyde. The reaction is known as Rosenmund reaction. This reduction can also be carried out by n-butyl tin hydride.