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Question

Which of the following reduce Tollen's reagent?

A
HCHO
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B
C6H5NHOH
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C
HCOOH
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D
C6H5NO2
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Solution

The correct options are
A C6H5NHOH
B HCOOH
D HCHO
Nitrobenzene does not reduce Tollen's reagent. The oxidation of nitrobenzene with ammoniacal silver nitrate solution does not occur.

HCHO+2[Ag(NH3)2]++H2OHCOOH+4NH3+2H++2Ag

PhNHOH+2[Ag(NH3)2]++2OHPhNO+2H2O+4NH3+2Ag

HCOOH+2[Ag(NH3)2]++2OHCO2+2H2O+4NH3+2Ag

Option D is correct.

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