Which of the following sets of reagents, used in the order shown , would successfully accomplish the conversion shown ?

C H_{3} C H_{2} C H_{2} M g B r

;

H_{3} O^{+}

;

P C C

C H_{2} C I_{2}

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C H_{3} C H_{2} C H_{2} M g B r

;

H_{3} O^{+}

;

H_{2} S O_{4}

h e a t P C C, C H_{2} C I_{2}

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(C_{6} H_{5})_{3} + P - - C H C H_{2} C H_{3}

B_{2} H_{6}

;

C H_{3} C O_{2} H

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(C_{6} H_{5})_{3} + P - - C H C H_{2} C H_{3}

;

H_{2} O

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Solution

The correct option is C $(C_{6} H_{5})_{3} + P - - C H C H_{2} C H_{3}$ , $B_{2} H_{6}$ ; $C H_{3} C O_{2} H$
$(P h)_{3} P^{\oplus} C H_{2}^{⊝} C H_{2} C H_{3}$ is used as a nucleophile which reacts with electrophilic carbon of carbonyl compounds.

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H_{2} S O_{4}

H_{2} S O_{4} + H_{2} O \to H_{3} O^{+} + H S O_{4}^{-}

Conjugate base of the following reaction is

Reaction:H2SO4 + H2O (reversibly giving)H3O^+ + HSO4^-

Ans gn:H3O^+ ,H2SO4

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