Which of the following solutions shows positive deviation from Raoult's law?

Acetone + Aniline

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Acetone + Ethanol

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Water + Nitric acid

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Chloroform + Benzene

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Solution

The correct option is B Acetone + Ethanol
Acetone + ethanol is an example of solutions showing positive deviation from Raoult's law. Since acetone-ethanol attractions are weaker that acetone - acetone and ethanol-ethanol attractions.

Hence, option B is correct.

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Which of the following solutions shows negative deviation from Raoult's law?

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