Which of the following species are hypervalent?
1. ClO−4
2. BF3
3. SO2−4
4. CO2−3
A hypervalent molecule is that molecule that contains one or more main group elements which contain more than eight electrons in their valence shells. So ClO−4 is hypervalent as Cl contains 14 electrons and SO2−4 is hypervalent as S contains 12 electrons.
BF3 and CO−23 are not hypervalent they have 6 and 8 electrons in their valence shells.
Hence option B is correct.