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Question

Which of the following statements is/are correct?
1.0 g mixture of CaCO3(s) and glass beads liberate 0.22 g of CO2 upon treatment with excess of HCl. Glass does not react with HCl.
CaCO3+2HClCO2+H2O+CaCl2
[Molecular weight of CaCO3=100 g/mol, CO2=44 g/mol and atomic weight of Ca=40 g]

A
The weight of CaCO3 in the original mixture is 0.5 g.
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B
Tile weight of calcium in the original mixture is 0.2 g.
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C
The weight percent of calcium in the original mixture is 40% Ca.
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D
The weight percent of calcium in the original mixture is 20% Ca.
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Solution

The correct options are
A The weight of CaCO3 in the original mixture is 0.5 g.
B Tile weight of calcium in the original mixture is 0.2 g.
C The weight percent of calcium in the original mixture is 20% Ca.
Weight of CaCO3=0.22×10044=0.5 g CaCO3
Moles of CaCO3= Moles of Ca=(0.2244)=0.005 mol
Weight of Ca=0.005×40=0.2 g Ca
Percentage of Ca =0.21.0×100=20% of Ca

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