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Question

Which of the following statements is not correct from the viewpoint of molecular orbital?

A
Be2 is not a stable molecule.
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B
He2 is not stable but He+2 is expected to exist.
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C
Bond strength of N2 is maximum amongst the homonuclear diatomic molecules belonging to the second period.
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D
The order of energies of molecular orbitals in F2 molecule is E(σ2s)<E(σ2s)<E(π2px)=E(π2py)<E(σ2p)<E(π2px)=E(π2py)<E(σ2p)
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Solution

The correct option is C The order of energies of molecular orbitals in F2 molecule is E(σ2s)<E(σ2s)<E(π2px)=E(π2py)<E(σ2p)<E(π2px)=E(π2py)<E(σ2p)
The order of energies of molecular orbitals in F2 molecule is:

E(σ2s)<E(σ2s)<E(σ2p)<E(π2px)=E(π2py)<E(π2px)=E(π2py)<E(σ2p)

The energy of σ2p orbital is lower than the energy of π2px and π2py orbitals.

Hence, the correct option is 'D'.

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