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Question

Which of the following will exhibit colour in aqueous solution ?

<!--td {border: 1px solid #ccc;}br {mso-data-placement:same-cell;}--> AIMPT 2010 Pre

A
Lu3+(Z=71)
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B
La3+(Z=57)
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C
Sc3+(Z=21)
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D
Ti3+(Z=22)
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Solution

The correct option is D Ti3+(Z=22)
The ion which have unpaired electron shows colour
(A) La=[Xe]5d16s2
La+3=[Xe]
0 unpaired electron.

(B) Ti=[Ar]3d24s2
Ti+3=[Ar]3d1
1 unpaired electron.

(C) Lu=[Xe]4f145d16s2
Lu+3=[Xe]4f14
0 unpaired electron.

(D) Sc=[Ar]3d14s2
Sc+3[Ar]
0 unpaired electron
Correct option is (b)

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