Which of the following will give a pair of enantiomers?

[C r (N H_{3})_{6}] [C o (C N)_{6}]

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[C o (e n)_{2} C l_{2}] C l

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[P t (N H_{3})_{4}] [P t C l_{6}]

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[C o (N H_{3})_{4} C l_{2}] N O_{2}

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Solution

The correct option is B $[C o (e n)_{2} C l_{2}] C l$
$[C o (e n)_{2} C l_{2}] C l$ can show optical isomerism for its cis-Isomer. Hence, it will form a pair of enantiomerism.

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Similar questions

Which of the following will give a pair of enantiomorphs?

$(e n = N H_{2} C H_{2} C H_{2} N H_{2})$

Match the correct pairs of isomers with their examples.

A)Ionisation (a) $P t (N H_{3})_{2} C l_{2}] [P t (N H_{3})_{4}]$

$[P t C l_{4}]$

B) Linkage (b) $[C r (N H_{3})_{6}] [C o (C N)_{6}]$ & $[C o (N H_{3})_{6} [C r (C N)_{6}]$

C)Coordination (c) $[C o (N H_{3})_{5} (N O_{2})] C l_{2}$ & $[C o (N H_{3})_{5} (O N O)] C l_{2}$

D)Polymerisation (d) $[C o (S O_{4}) (N H_{3})_{5}] B r$ & $[C o (B r (N H_{3})_{5}] S O_{4}$

[C o {(N H_{3})}_{4} C l_{2}] N O_{2}

[C o {(N H_{3})}_{4} C l N O_{2}] C l

[C o (e n)_{2} C l_{2}]^{+}

[C o (N H_{3})_{4} C l_{2}]^{+}

- [C o (N H_{3})_{4} C l_{2}]^{+}

- [C o (e n)_{2} C l_{2}]^{+}

- [C o (e n)_{2} C l_{2}]^{+}

[C o (e n)_{3}]^{3 +}

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