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Introduction to Optical Isomerism

Which of the ...

Question

Which of the following will give a pair of enantiomorphs?

A

[P t {(N H_{3})}_{4}] [P t C l_{6}]

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B

[C o {(N H_{3})}_{4} C l_{2}] N O_{2}

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C

[C r {(N H_{3})}_{6}] [C o {(C N)}_{6}]

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D

[C o {(e n)}_{2} C l_{2}] C l

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Solution

The correct option is D $[C o {(e n)}_{2} C l_{2}] C l$

Molecules or compounds which are mirror images of each other but are not identical and they rotate the plane of polarised light equally but in opposite directions are called as enantiomorphs.
Hence option D is correct.

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Similar questions

Which of the following will give a pair of enantiomorphs?

$(e n = N H_{2} C H_{2} C H_{2} N H_{2})$

Match the correct pairs of isomers with their examples.

A)Ionisation (a) $P t (N H_{3})_{2} C l_{2}] [P t (N H_{3})_{4}]$

$[P t C l_{4}]$

B) Linkage (b) $[C r (N H_{3})_{6}] [C o (C N)_{6}]$ & $[C o (N H_{3})_{6} [C r (C N)_{6}]$

C)Coordination (c) $[C o (N H_{3})_{5} (N O_{2})] C l_{2}$ & $[C o (N H_{3})_{5} (O N O)] C l_{2}$

D)Polymerisation (d) $[C o (S O_{4}) (N H_{3})_{5}] B r$ & $[C o (B r (N H_{3})_{5}] S O_{4}$

Q. Which of the following is incorrect statement regarding A (

[C o (e n)_{2} C l_{2}]^{+}

[C o (N H_{3})_{4} C l_{2}]^{+}

Q. Which of the following compounds show optical isomerism?
I. cis

- [C o (N H_{3})_{4} C l_{2}]^{+}

- [C o (e n)_{2} C l_{2}]^{+}

- [C o (e n)_{2} C l_{2}]^{+}

[C o (e n)_{3}]^{3 +}

[C o (N H_{3})_{4} C l_{2}] N O_{2}

[C o (N H_{3})_{4} C l N O_{2}] C l

exhibit which type of isomerism?

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