Which of the following will have the least bond angle?
A
CH4
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B
NH3
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C
PH3
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D
H2O
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Solution
The correct option is C
PH3
PH3 is a trigonal pyramidal molecule. The length of the P−H bond is 1.42 Å and the H−P−H bond angles are 93.5°, which is the least among the given compounds.