Which of the following will not give Claisen condensation product?

(C H_{3})_{3} C C O O E t

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H_{2} C = C H C H_{2} C H_{2} C O O E t

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C_{6} H_{5} C H_{2} C O O E t

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(C H_{3})_{2} C H C H_{2} C O O E t

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Solution

The correct option is A $(C H_{3})_{3} C C O O E t$

From mechanism it can be seen that, to perform Claisen condensation reaction reactant should have alpha hydrogen, here as reactant $(C H_{3})_{3} C C O O E t$ dont have any alpha H so it will not give this reaction.

Option A is correct.

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