Which of the following will not give ethyl amine?

The reduction of nitroethane with Sn/HCl.

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The reduction of nitroethane with LiAlH

_{4}

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The reduction of methyl cyanide with LiAlH

_{4}

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The reduction of methyl isocyanide with sodium / ethanol.

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Solution

The correct option is D The reduction of methyl isocyanide with sodium / ethanol.
The reduction of methyl isocyanide with sodium / ethanol will give dimethyl amine.
$C H_{3} N C N a / C_{2} H_{5} O H - ------- \to C H_{3} N H C H_{3}$

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S n / H C l

L i A l H_{4}

L i A l H_{4}

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