The correct option is B Ti
The elements or ions which have unpaired electrons have the ability to show the paramagnetic behaviour.
The electronic configuration of Ar is
1s22s22p63s23p6
So number of unpaired electrin in Ar=0
The electronic configuration of Ti is
1s22s22p63s23p64s23d2
So number of unpaired electrin in Ti=2
The electronic configuration of Sc3+ is
1s22s22p63s23p6
So number of unpaired electrin in Sc3+=0
The electronic configuration of V5+ is
1s22s22p63s23p6
So number of unpaired electrin in V5+=0