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Question

Which of the following would you expect to have the lowest boiling point?

A
H2O
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B
NH3
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C
CH4
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D
H2
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Solution

The correct option is D H2
The boiling point of a substance depends on strength of intermolecular forces. The higher the intermolecular forces, the higher the boiling point. Here H2O,NH3 has hydrogen bonding, and CH4 has Vanderwall forces. So, H2 which has the least intermolecular forces has a low boiling point.
So, the order is H2O>NH3>CH4>H2

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