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Question

Which of the followings is not a intramolecular redox reaction?

A
NH4NO2N2+2H2O
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B
NH4NO3N2O+2H2O
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C
2KClO32KCl+3O2
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D
2H2O22H2O+O2
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Solution

The correct option is D 2H2O22H2O+O2
Intramolecular redox reactions are the reactions in which one element of a compound is oxidised while the other is reduced.
Disproportionation is a specific type of redox reaction in which a species is simultaneously reduced and oxidised to form two different products.
H2O2H2O+O2
-1 -2 0
It is a disproportionation reaction and not intramolecular redox reaction .
NH4NO2N2+2H2O
-3 +3 0
NH4NO3N2O+2H2O
-3 +5 +1
2KClO32KCl+3O2
+5 -1 0
All these three are intramolecular redox reaction.

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