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Question

Which of these is o, p-directing and deactivating group?

A
F
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B
Cl
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C
Br
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D
All of these
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Solution

The correct option is D All of these
X (halogen group)has two effects I & +M.
Due to the I group, it reduces the electron density of benzene so halobenzene is less reactive than benzene for electrophilic substitution reaction.
But due to the +M effect, it is ortho, para directing(resonance effect predominates over inductive effect) and in halobenzene, further substitution takes place at ortho and para positions.

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