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Question

Which one is balanced net ionic equations for the following reactions in acidic solution:
HNO2(aq)NO3+NO(g)

A
3HNO2(aq)NO3(aq)+2NO(g)+H2O+H+(aq)
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B
4HNO2(aq)3NO3+2NO(g)+H2O+H++e
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C
3HNO2(aq)NO3+2NO(g)+H2O+H++e
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D
4HNO2(aq)NO3+2NO(g)+H2O+H++e
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Solution

The correct option is A 3HNO2(aq)NO3(aq)+2NO(g)+H2O+H+(aq)
Steps for Balancing redox reactions:
  1. Identify the oxidation and reduction half .
  2. Find the oxidising and reducing agent.
  3. Find the n-factor of oxidising and reducing agent.
  4. Balance atom undergoing oxidation and reduction.
  5. Cross multiply the oxidising or reducing agent with n-factor.
  6. Balance atoms other than oxygen and hydrogen.
  7. Balancing oxygen atoms
  8. Balancing hydrogen atoms
  9. Balance charge
For acidic medium:
As soon as we add x H2O units, we add 2x H+ ions on the opposite side.

nf=(|O.S.ProductO.S.Reactant|×number of atom
+3HNO2(aq)+5NO3++2NO(g)
+3HNO2(aq)+5NO3 oxidation
nf=(|53|×1=2
+3HNO2(aq)+2NO(g) reduction
nf=(|23|×1=1

Balance atom undergoing oxidation and reduction.
3HNO2(aq)NO3+2NO(g)

Balance oxygen atom.
3HNO2(aq)NO3(aq)+2NO(g)+H2O

Balance hydrogen.
3HNO2(aq)NO3(aq)+2NO(g)+H2O+H+(aq)

balance charge
charge in reactant side = 0
charge in product side = 0
so the balanced equation is 3HNO2(aq)NO3(aq)+2NO(g)+H2O+H+(aq)

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