Which one of the following amide will not undergo Hoffmann bromamide reaction?

{C H}_{3} C O {N H}_{2}

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{C H}_{3} C O N H {C H}_{3}

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C_{6} H_{5} C O {N H}_{2}

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{C H}_{3} {C H}_{2} C O {N H}_{2}

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Solution

The correct option is A ${C H}_{3} C O N H {C H}_{3}$
For hoffmann bromamide reaction to take place nitrogen should have 2 hydrogens attached with it. Therefore, $C H_{3} C O N H C H_{3}$ will not undergo hoffmann bromamide.

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One of the following amide will not undergo Hoffmann bromamide reaction:

1^{o}

N -

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