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Question

Which one of the following carbocation is the most stable?

A
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B
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C
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D
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Solution

The correct option is C
CH3 group when present at ortho or para position stabilises the benzylic cation through hyperconjugation. At meta postion it operates +I effect only.
NO2 group shows strong electron withdrawing effect and hence it destabilises the carbocation.
So the stability will order be:
c>d>a>b

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