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+I Effect

Which one of ...

Question

Which one of the following is correct ?
I. $C H_{3} - C H_{2} - C D_{2}^{+}$
II. $C H_{3} - C H_{2} - C T_{2}^{+}$
(Explain on the basis of inductive effect)

I is more stable than II

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II is more stable than I

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Both are equally stable

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Stability criterion cannot be applied in this case

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Solution

The correct option is B II is more stable than I
The $+ I$ effect of $- T$ is higher than that of $- D$ due to the higher electronegativity of $- D$ than that of $- T$ . Therefore, II carbocation is more stable than I carbocation.

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