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Question

Which one of the following is wrong about molecularity of a reaction?

A
It may be whole number or fractional
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B
It is the number of molecules of the reactants taking part in a single step chemical reaction
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C
It is always equal to the order of elementary reaction
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D
It is always a whole number
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Solution

The correct option is A It may be whole number or fractional
The molecularity of a reaction is defined as the number of molecules or ions that participate in the rate determining step. A mechanism in which two reacting species combine in the transition state of the rate-determining step.

Molecularity of a reaction can never be fractional. It is always a whole number.

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