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Byju's Answer
Standard XII
Chemistry
Enthalpy
Which one of ...
Question
Which one of the following pairs is obtained on heating ammonium dichromate?
A
N
2
and
H
2
O
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B
H
2
O and
H
2
O
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C
N
O
2
and
H
2
O
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D
NO and
N
O
2
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Solution
The correct option is
A
N
2
and
H
2
O
On heating ammonium dichromate;
N
2
,
H
2
O
and
C
r
2
O
3
are formed.
(
N
H
4
)
2
C
r
2
O
7
(
s
)
⟶
N
2
(
g
)
+
4
H
2
O
(
g
)
+
C
r
2
O
3
(
s
)
Δ
H
=
−
429
k
c
a
l
/
m
o
l
Option (A) is correct.
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Similar questions
Q.
(a) Pyrolusite on heating with
K
O
H
in the presence of air gives a dark green compound (A). The solution of (A) on treatment with
H
2
S
O
4
gives a purple coloured compound (B), which gives following reactions:
(i)
K
I
on reaction with alkaline solution of (B) changes into a compound (C).
(ii) The colour of the compound (B) disappears on treatment with the acidic solution of
F
e
S
O
4
.
(iii) With conc.
H
2
S
O
4
compound (B) gives (D) which can decompose to yield (E) and oxygen. Identify (A) to (E) and write balanced chemical equations for the formation of (A) and (B) and for the steps (i) to (iii).
(b) Complete and balance the following chemical equations.
(i)
A
u
+
H
C
l
+
H
N
O
3
⟶
.
.
.
.
.
.
.
.
+
.
.
.
.
.
.
.
.
+
H
2
O
(ii)
C
+
H
N
O
3
(
c
o
n
c
.
)
⟶
C
O
2
+
.
.
.
.
.
.
.
.
+
H
2
O
(iii)
S
n
+
K
O
H
(
h
o
t
)
+
H
2
O
⟶
.
.
.
.
.
.
.
+
.
.
.
.
.
.
.
(iv)
C
u
(
O
H
)
2
+
N
H
4
N
O
3
+
N
H
4
O
H
⟶
.
.
.
.
.
+
H
2
O
Q.
The following data were obtained for
H
2
O
and
H
2
S
:
Formula Mass
Freezing Point(
o
C)
Boiling Point(
o
C)
H
2
O
18
0
100
H
2
S
34
−
83
−
60
Which of the following will best describe the difference in physical properties among these two compound?
Q.
Identify the reducing agent and the oxidising agent in the reaction (i) and (ii) respectively
(
i
)
Mn
O
2
+
4HCl
→
MnC
l
2
+ 2
H
2
O + C
l
2
(
i
i
)
CuO +
H
2
→
Cu +
H
2
O
Q.
Z
n
gives
H
2
gas with
H
2
S
O
4
and
H
C
l
but not with
H
N
O
3
Q.
Given
N
O
−
2
+
H
2
O
⇋
H
N
O
2
+
O
H
−
,
K
b
=
2.22
×
10
−
11
Thus, the degree of hydrolysis of 0.04
M
N
a
N
O
2
solution is:
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