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Question

Which one of the following paramagnetic in nature?

A
CuCl2
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B
CaCl2
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C
CdCl2
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D
All of these
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Solution

The correct option is C CuCl2
Option (A) is correct.
In CuCl2, Cu is in +2 oxidation state.
Electronic configuration of Cu2+ is [Ar],3d9, and is coloured and paramagnetic due to presence of an unpaired electron in the 3d sub-orbital.

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