Which one of the following reaction is not associated with the Solvay's process for manufacturing of sodium carbonate?

N H_{3} + H_{2} O + C O_{2} \to N H_{4} H C O_{3}

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2 N a O H + C O_{2} \to N a_{2} C O_{3} + H_{2} O

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2 N a H C O_{3} \to N a_{2} C O_{3} + H_{2} O + C O_{2}

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N a C l + N H_{4} H C O_{3} \to N a H C O_{3} + N H_{4} C l

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Solution

The correct option is B $2 N a O H + C O_{2} \to N a_{2} C O_{3} + H_{2} O$
Solvay process is generally used for the preparation of sodium carbonate. The following reaction are involved in this process.

$2 N H_{3} + H_{2} O + C O_{2} \to (N H_{4})_{2} C O_{3}$

$(N H_{4})_{2} C O_{3} + C O_{2} + H_{2} O \to 2 N H_{4} H C O_{3}$

$N H_{4} H C O_{3} + N a C l \to N H_{4} C l + N a H C O_{3}$

$2 N a H C O_{3} \to N a_{2} C O_{3} + H_{2} O + C O_{2}$

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