Which one of the following reactions is an example of auto-catalysis ?
A
2AsH3(s)→2As(s)+3H2(g)
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B
N2(g)→3H2(g)Fe(g)→2NH3(g)
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C
2SO2(g)→O2(g)NO(g)→2SO3(g)
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D
C12H22OH(l)+H2O(l)H−(l)→C6H12O6(l)HC6H12O6(l)
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Solution
The correct option is D2AsH3(s)→2As(s)+3H2(g) Auto-catalysis is defined as the reaction that is catalyzed by one of its product. in auto-catalysis product of reaction acts as a catalyst for the reaction. In auto-catalysis the initial rate of reaction rises as the catalytic product is formed instead of decreasing steadily.
for example: the free arsenic produced by decomposition of arsine auto catalyses the reaction. The thermal decomposition of Arsine produces arsenic and hydrogen. 2AsH3 forms 2As + 3H2