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Question

Which one of the following reactions is consistent with the Markovnikov's rule?

A
(CH3)2CHCH=CH2+H2O(CH3)2CHCH2CH2OH
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B
CH3CH2CH=CH2+H2OCH3CH2CH2CH2OH
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C
CH3CH=CHCH3+H2OCH3CH2CH(CH3)OH
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D
H2C=CHCH3+H2OH3CCH(OH)CH3
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Solution

The correct option is D H2C=CHCH3+H2OH3CCH(OH)CH3

Markownikoff's rule can be stated that with the addition of a protic acid HX to an unsymmetrical alkene the hydrogen atom is added to the carbon with the greater number of hydrogen atoms while the X component is added to the carbon with the fewer number of hydrogen atoms.
Anti-Markownifkoff's reaction is exactly the opposite of Markovnikov reaction

In the above question, all reactions are anti-Markovnikov reactions except option-4. this reaction is consistent with Markovnikov' rule.

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