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Question

Which one of the following shows geometrical isomerism : CHCl=CHCl, CH2=CCl2,and CCl2=CHCl.

A
CHCl=CHCl
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B
CH2=CCl2
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C
CCl2=CHCl
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D
None of the above
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Solution

The correct option is A CHCl=CHCl
Condition to show geometrical isomerism : XYC=CXY
X and Y must have different groups/atoms attached to carbon on the same side of double bond.
Among given compounds, only CHCl=CHCl shows geometrical isomerism.
Other two have identical atoms on the same side of double bond; therefore, they can not show cis-trans isomerism.

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