Which one of the following species attracts to an external magnetic field ?
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JEE Main 2021
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Solution
CN−andCO are strong field ligands and causes pairing of electrons. Whereas H2O is weak field ligand so do not cause pairing, generally. [Fe(H2O)6]3+
So, [Fe(H2O)6]3+ is paramagnetic. In the rest of the complexes no unpaired electron is present hence they are diamagnetic. Paramagnetic substances get weakly attracted by external magnetic field whereas diamagnetic gets weakly repelled.
[Ni(CN)4]2−→3d8(All electrons are paired) [Co(CN)6]3−→3d6(All electrons are paired) [Ni(CO)4]→3d8(All electrons are paired)