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Question

Which one of the following species attracts to an external magnetic field ?

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Solution

CN and CO are strong field ligands and causes pairing of electrons. Whereas H2O is weak field ligand so do not cause pairing, generally.
[Fe(H2O)6]3+


So, [Fe(H2O)6]3+ is paramagnetic. In the rest of the complexes no unpaired electron is present hence they are diamagnetic. Paramagnetic substances get weakly attracted by external magnetic field whereas diamagnetic gets weakly repelled.

[Ni(CN)4]23d8 (All electrons are paired)
[Co(CN)6]33d6 (All electrons are paired)
[Ni(CO)4]3d8 (All electrons are paired)

Hence, option (b) is correct.

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