The correct option is C +64.8kcal mol−1
The reaction in which the value of ΔH>0 has the energy of products more than that of the reactants.
And the reaction in which the energy of product is much more will have the value of ΔH>>0.
And since, the product with more energy value is less stable, hence the least stable product is the one with maximum value of ΔH.
Hence, answer is option D.