Which one of the following will not show geometrical isomerism?

[C r {(N H_{3})}_{4} C l_{2}] C l

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[C o {(e n)}_{2} C l_{2}] C l

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[C o {(N H_{3})}_{5} N O_{2}] C l_{2}

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[P t {(N H_{3})}_{2} C l_{2}]

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Solution

The correct option is A $[C o {(N H_{3})}_{5} N O_{2}] C l_{2}$
For cis-trans geometrical isomerism, we should have at least two same ligands.

Therefore, in $[C o (N H_{3})_{5} N O_{2}] C l_{2}$ we will not observe geometrical isomerism.

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Similar questions

Q. Which among the following species exhibit geometrical isomerism?

[C o (N H_{3})_{4} (H_{2} O)_{2}] C l_{2}, [N i (H_{2} O)_{6}] C l_{2}, [C o (H_{2} O)_{5} C l] C l, [P t (N H_{3})_{2} C l_{2}], [P t (e n) C l_{2}], [P t (e n)_{2} C l_{2}], [P b C l_{2} B r I], [C o (N H_{3}) 4 C l_{2}], [C o (e n)_{2} B r_{2}]

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Q. Assertion :Complexes containing three bidentate ligands do not show optical activity. Reason: Octahedral complex

[C o (N H_{3})_{4} C l_{2}] C l

shows geometrical isomerism.

Q. Which of the following will not show geometrical isomerism?

Statement - 1: Complexes containing three bidentate ligands do not show optical activity.
Statement - 2: Octahedral complex $[C o (N H_{3})_{4} C l_{2}] C l$ shows geometrical isomerism.

Q. Which of the following(s) will not show geometrical isomerism?

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Which one of the following will not show geometrical isomerism?

The correct option is A [Co(NH3)5NO2]Cl2For cis-trans geometrical isomerism, we should have at least two same ligands.Therefore, in [Co(NH3)5NO2]Cl2 we will not observe geometrical isomerism.

The correct option is A $[C o {(N H_{3})}_{5} N O_{2}] C l_{2}$
For cis-trans geometrical isomerism, we should have at least two same ligands.

Therefore, in $[C o (N H_{3})_{5} N O_{2}] C l_{2}$ we will not observe geometrical isomerism.