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Question

Which oxide of nitrogen is formed on subjecting nitric acid to heat or light?

A
N2O4
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B
N2O5
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C
NO2
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D
N2O
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Solution

The correct option is C NO2
Nitric acid is subject to thermal or light decomposition and for this reason it was often stored in brown glass bottles:
4 HNO3 → 2 H2O + 4 NO2 + O2.
This reaction may give rise to some non-negligible variations in the vapor pressure above the liquid because the nitrogen oxides produced dissolve partly or completely in the acid.

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