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Question

Which reaction cannot be used for the preparation of the halogen acid?

A
2KBr+H2SO4(Conc)K2SO4+2HBr
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B
NaCl+H2SO4(Conc)NaHSO4+HCl
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C
NaHSO4+NaCl(Conc)Na2SO4+HCl
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D
CaF2+H2SO4(Conc)CaSO4+2HF
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Solution

The correct option is A 2KBr+H2SO4(Conc)K2SO4+2HBr
HBr can be synthesized by a variety of methods. It may be prepared in the laboratory by distillation of a solution of sodium bromide or potassium bromide with phosphoric acid or sulfuric acid:
KBr+H2SO4K2SO4+HBr

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