Which reagent is used for the conversion of (A) to (B) ?
A
H2+[RhCl(Ph3P)3]
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B
NH2NH2+O2
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C
MMPPinethanol/H3O⨁
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D
Sia2BH+CH3COOH
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Solution
The correct option is BSia2BH+CH3COOH a) H2+[RhCl(Ph3P)3] and (b) NH2NH2+O2 reduce both the (C=C) to (C-C) (syn-addition). (c) MMPP in ethanol /H3O⨁ is used for the antihydroxylation of both (C=C) to (−C|(OH)−C|(OH)− (d) Sia2BH+CH3COOH reduces only unhindered (C=C) to (C-C). The reagent used for the conversion of (A) to (B) is Sia2BH+CH3COOH