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Question

Which reagent is used for the conversion of (A) to (B) ?
248746_19b3dfd7a3224753b74709cb464ef194.png

A
H2+[RhCl(Ph3P)3]
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B
NH2NH2+O2
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C
MMPPinethanol/H3O
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D
Sia2BH+CH3COOH
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Solution

The correct option is B Sia2BH+CH3COOH
a) H2+[RhCl(Ph3P)3] and (b) NH2NH2+O2 reduce both the (C=C) to (C-C) (syn-addition).
(c) MMPP in ethanol /H3O is used for the antihydroxylation of both (C=C) to (C|(OH)C|(OH)
(d) Sia2BH+CH3COOH reduces only unhindered (C=C) to (C-C).
The reagent used for the conversion of (A) to (B) is
Sia2BH+CH3COOH

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