Which statement is/are correct?
i) Physical adsorption is due to Van der Waal's forces
ii) Physical adsorption decreases at high temperature
iii) Physical adsorption is irreversible
iv) Enthalpy for a chemical adsorption is generally lesser than that of physical adsorption
i, ii
Physisorption- The process is reversible i.e. desorption of the gas occurs by increasing the temperature or decreasing the pressure.
It takes place by the help of non-covalent attraction between adsorbate and adsorbent making the process reversible.
&enthalpy for a chemical adsorption is higher than that of physical adsorption