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Standard XII
Chemistry
Assigning Oxidation Numbers
Why does ceri...
Question
Why does cerium have 4 oxidation states?
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Solution
Cerium:
Cerium is an atomic number 58 and has the atomic symbol Ce.
Cerium is a silvery-white soft, ductile metal that tarnishes when exposed to air.
Oxidation State of Cerium:
Cerium belongs to the lanthanide series of elements.
The electronic configuration of Cerium is:
[
Xe
]
4
f
2
5
d
0
6
s
2
As a result, it can lose the outermost four electrons in the s and f orbitals to attain the inert gas electronic configuration.
Hence, the oxidation state of Cerium is +4.
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Why does cerium show +4 oxidation state?
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Although +3 oxidation state is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?
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Cerium (Z=58) shows +4 oxidation state because:
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Generally lanthanides element show +3 oxidation state but cerium shows +4 oxidation state.why ?
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