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Bond Angle

Why square pl...

Question

Why square planar complex contain d_x2_-y2 orbital.

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Solution

$I n s q u a r e p l a n a r c o m p l e x e s t h e r e i s o n l y o n e d o r b i t a l i s i n v o l v e d i n s t r o n g σ b o n d i n g n a m e l y d_{x^{2} - y^{2}} o r b i t a l . T h e d_{Z^{2}} o r b i t a l i n t e r a c t s w e a k l y w i t h t h e f o u r l i g a n d σ v a l e n c e o r b i t a l s a s t h e y a r e d i r e c t e d a l o n g t h e Z a x i s$

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