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Magnetic Moment Examples

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Question

With the help of Valence bond theory account for hybridisation, geometry and magnetic property of $[N i (C N)_{4}]^{2 -}$ complex ion $[Z$ for $N i = 28]$ .

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Solution

$N i^{2 +}$ ion with outer electronic configuration $3 d^{8}$ undergoes $d s p^{2}$ hybridisation which results in square planar geometry. Since all electrons are paired, the complex is diamagnetic.

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