Write all the geometrical isomers of [Pt(NH₃)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?

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Solution

[Pt(NH₃)(Br)(Cl)(py)

From the above isomers, none will exhibit optical isomers. Tetrahedral complexes rarely show optical isomerization. They do so only in the presence of unsymmetrical chelating agents.

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Write all the geometrical isomers of $[P t (N H_{3}) (B r) (C l) (p y)]$ and how many of these will exhibit optical isomers?

C_{3} H_{5} C l

{[C o {C l}_{2} (e n) {({N H}_{3})}_{2}]}^{+}

Which of the following will have optical isomers without having geometrical isomers?

Draw all the isomers (geometrical and optical) of:
${[C o C l_{2} {(e n)}_{2}]}_{2}^{+}$

${[C o (N H_{3}) C l {(e n)}_{2}]}_{2}^{2 +}$

${[C o {(N H_{3})}_{2} C l_{2} (e n)]}_{2}^{+}$

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