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Question

Write just the shape and hybridization in PCl5 and SF6 molecule.

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Solution

  • PCl5 is sp3d hybridised molecule. It has trigonal bipyramidal geometry. In this case, the axial bonds are slightly longer than the equatorial bonds. This is because the axial bonds experience greater repulsion from other bonds than the equatorial bonds.
  • SF6 is the molecule formed by sp3d2 hybridization of SF bond. The geometry and shape of SF6 molecule are octahedral.

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