For writing the reactants in molecular forms, the requisite number of chloride ions are added.
2Fe3++6Cl−+Sn2++2Cl−
or 2FeCl3 + SnCl2
Similarly 8Cl− ions are added on RHS to neutralise the charges.
2Fe2++4Cl−+Sn4++4Cl−
or 2FeCl2 + SnCl4
Thus, the balanced molecular equation is
2FeCl3+SnCl2=2FeCl2+SnCl4