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Hydrohalogenation of Alkenes

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Question

Write the formula of Tetraminodichloroplatinum(IV) chloride. How is propene converted into $1$ -bromopropane and $2$ -bromopropane ?

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Solution

Tetraminodichloroplatinum(IV) chloride $[P t {C l}_{2} {(N H_{3})}_{4}] {C l}_{2}$
Propene converted into $1$ -bromopropane
$C H_{3} C H = C H_{2} + H B r P e r o x i d e - ---------- \to C H_{3} C H_{2} C H_{2} B r 1 - b r o m o p r o p a n e$
Propene converted into $2$ -bromopropane
$C H_{3} C H = C H_{2} + H B r M K r u l e - ----------- \to C H_{3} C H B r C H_{3} 2 - b r o m o p r o p a n e$

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1 - b r o m o p r o p a n e

2 - b r o m o p r o p a n e

H B r

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How the following conversions can be carried out?

(i) Propene to propan-1-ol

(ii) Ethanol to but-1-yne

(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol

(v) Benzene to 4-bromonitrobenzene

(vi) Benzyl alcohol to 2-phenylethanoic acid

(vii) Ethanol to propanenitrile

(viii) Aniline to chlorobenzene

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane

(xi) Ethyl chloride to propanoic acid

(xii) But-1-ene to n-butyliodide

(xiii) 2-Chloropropane to 1-propanol

(xiv) Isopropyl alcohol to iodoform

(xv) Chlorobenzene to p-nitrophenol

(xvi) 2-Bromopropane to 1-bromopropane

(xvii) Chloroethane to butane

(xviii) Benzene to diphenyl

(xix) tert-Butyl bromide to isobutyl bromide

(xx) Aniline to phenylisocyanide

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