Tetrachloroethene (Cl2C=CCl2) was earlier used as solvent for dry cleaning. The process using this compound is now being replaced by a process, where liquefied carbon dioxide, with a suitable detergent, is used. Replacement of halogenated solvent by liquid CO2 will result in less harm to groundwater.
Bleaching of paper-
Chlorine gas was used earlier for bleaching paper. These days, hydrogen peroxide (H2O2) with a suitable catalyst, which promotes the bleaching action of hydrogen peroxide, is used.
Synthesis of chemicals-
Ethanal (CH3CHO) is now commercially prepared by one step oxidation of ethene in the presence of an ionic catalyst in an aqueous medium with a yield of 90%.