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Byju's Answer
Standard XII
Chemistry
Nomenclature of Coordination Compounds
Write the IUP...
Question
Write the IUPAC name of the following
(i)
P
t
C
l
4
⋅
5
N
H
3
(gives
4
ions in solution)
(ii)
P
t
C
l
4
⋅
2
K
C
l
(gives
3
ions in solution)
(ii)
I
r
C
l
3
⋅
3
N
H
3
(no
C
l
−
ion is precipitated)
(iv)
C
o
C
l
3
⋅
4
N
H
3
m(one
C
l
is precipitated by
A
g
N
O
3
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Solution
(i)Pentaamminechloroplatinum(II) chloride.
(ii)Potassiumhexachloroplatinate(II)
(iii)Triammivetrichlororidium(III)
(iv)Tetraammine dichlorocobalt(III)
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Similar questions
Q.
In the complex
C
o
C
l
3
⋅
5
N
H
3
, one
C
l
−
ion satisfies primary and secondary valencies of cobalt(III).
Q.
On the basis of Werner's theory explain, why cobalt amine complex,
C
o
C
l
3
4
N
H
3
when treated with
A
g
N
O
3
solution precipitates only one
C
l
−
ion even though there are three
C
l
−
ions?
Q.
Consider the following complexes.
(i)
K
2
P
t
C
l
6
(ii)
P
t
C
l
4
⋅
2
N
H
3
(iii)
P
t
C
l
4
⋅
3
N
H
3
(iv)
P
t
C
l
4
⋅
5
N
H
3
Their electrical conductances in aqueous solutions are:
Q.
Assertion :
C
o
C
l
3
⋅
4
N
H
3
gives two ions when ionised. Reason: Complex is
[
C
o
(
N
H
3
)
4
]
C
l
3
.
Q.
Give the iupac names
[Pt(NH3)4][PtCl4]
[Pt(NH3)4Cl2][PtCl4]
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