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Question

Write the structure of the major organic product in each of the following

(a)CH3CH2CH2Cl+NaIAcetone−−−−

(b) (CH3)3CBr+KOHEthanol,heat−−−−−−−

(c) CH3CH(Br)CH2CH3+KOHWater−−−

(d) CH3CH2Br+KCNAq.ethanol−−−−−

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Solution

a. CH3CH2CH2Cl+NalAcetone−−−−ΔCH3CH2CH2I+NaCl

b. CH3CH3|C|CH3Br+KOHEhtanol−−−−−−EliminationCH3CH3|C=CH2+KBr+H2O

c. CH3CH|BrCH2CH3+NaOHWater−−−SN2CH3CH|OHCH2CH3

d. CH3CH2Br+KCNAq−−−−−−−ethanol(SN2)CH3CH2C=N+NBr

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