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Question

XY2 dissociates as, XY2(g)XY(g)+Y(g)
Initial pressure of XY2 is 600 mm Hg. The total pressure at equilibrium is 800 mm Hg. Assuming volume of system to remain constant, the value of Kp is:

A
50
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B
100
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C
20
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D
400
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Solution

The correct option is B 100
XY2(g)XY(g)+Y(g)
t=0 P0 0 0
t=teq P0(1α) P0α P0α

400mn 200 200mn
Given P0=600mn
P0(1+α)=800mn
1+α=4/3
α=1/3
KP=200×200400=100

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