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Question

1 mol of ferric oxalate is oxidized by x mol of MnO4 and 1 mol of ferrous oxalate is oxidized by y mol of MnO4 in acidic medium. The ratio xy is ____.

A
2:1
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B
1:2
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C
3:1
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D
1:3
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Solution

The correct option is A 2:1
Ferric oxylate Fe2(C2O4)32Fe+3+3C2O24
ferrous oxylate FeC2O4Fe+2+C2O24
oxidizing agent is MnO4
2 mol Fe3 in ferric oxidized
1 mol Fe+2 in ferrous oxidized
Ratio xy=21

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