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46. Highest C...

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46. Highest C-O bond length found in 1) [Mn(CO)6]+ 2) [Cr(CO)6] 3) [V(CO)6]- 4) same in all.

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Q. Among the metal carbonyls

[M n (C O)_{6}]^{+}, [T i (C O)_{6}], [C r (C O)_{6}]

[V (C O)_{6}]^{-}

C - O

bond order would be lowest in :

Q. In which complex is the

C - O

bond length maximum?

Q. Consider the following complexes

[V (C O)_{6}]^{-}, [C r (C O)_{6}]

[M n (C O)_{6}]^{+}

. Then incorrect statement(s) about metal carbonyls is /are

I R

stretchin frequencies of free

C O

C O

[V (C O)_{6}]^{-}, [C r (C O)_{6}]^{-}

[M n (C O)_{6}]^{-}

2143 c m^{- 1}, 1860 c m^{- 1}, 2000 c m^{- 1}

2090 c m^{- 1}

, respectively. Then correct statement about metal carbonyls is?

Which of the following has longest C-O bond length? (Free C-O bond length in CO is 1.128 A.)

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